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PUBLICATIONS
References and Links to Papers
21. “Multi-Catalytic Metal-Based Homogeneous-Heterogeneous Systems in Organic Chemistry”
Juan Camilo Arango-Daza, Miguel A. Rivero-Crespo
Chem. Eur. J. 2024, e202400443. DOI: 10.1002/chem.202400443.
Prior to Stockholm University
20. “Mechanistic Investigation of the Rhodium-Catalyzed Transfer Hydroarylation Reaction Involving Reversible C–C Bond Activation”
Marius D. R. Lutz, Sven Roediger, Miguel A. Rivero-Crespo, Bill Morandi
J. Am. Chem. Soc. 2023, 145, 26657 -– 26666. DOI: 10.1021/jacs.3c07780.
19. “Intimate ruthenium–platinum nanoalloys supported on carbon catalyze the hydrogenation and one–pot hydrogenation–coupling reaction of oxidized amino derivatives”
M.A. Rivero-Crespo, P. Rubio–Marqués, M. Mon, J. Oliver–Meseguer, A. Leyva–Pérez
Catal. Sci. Technol., 2023, 13, 2508 – 2516. DOI: 10.1039/D2CY01846B.
18. “Mechanistic Investigation of the Nickel-Catalyzed Metathesis between Aryl Thioethers and Aryl Nitriles”
P. Boehm,+ P. Müller,+ P. Finkelstein, M.A. Rivero-Crespo, M.-O. Ebert, N. Trapp, B. Morandi
J. Am. Chem. Soc. 2022, 144, 29, 13096 – 13108. DOI: 10.1021/jacs.2c01595.
17. “Activity-Based Approach for Selective Molecular CO2 Sensing”
O. Green,+ P. Finkelstein,+ M.A. Rivero-Crespo, M.D.R. Lutz, M.K. Bogdos, M. Burger, J.-C. Leroux, B. Morandi.
J. Am. Chem. Soc. 2022, 144, 19, 8717-8724. DOI: 10.1021/jacs.2c02361.
16. “Pd-Catalyzed, Direct Deoxygenative Arylation of Alcohols with Boronic Acids via Transient Formation of Non-Innocent Isoureas”
G. Toupalas, G. Thomann,+ L. Schlemper,+ M.A. Rivero-Crespo, H.L. Schmitt, B. Morandi
ACS Catal. 2022, 12, 14, 8147 – 8154. DOI: 10.1021/acscatal.2c01858.
15. “Preparation of Recyclable and Versatile Porous Poly(aryl thioether)s by Reversible Pd-Catalyzed C–S/C–S Metathesis”
M.A. Rivero–Crespo, G. Toupalas and B. Morandi
J. Am. Chem. Soc. 2021, 143, 50, 21331 – 21339. DOI: 10.1021/jacs.1c09884.
14. “Acid Catalysis with Alkane/Water Microdroplets in Ionic Liquids”
R. Greco, V. Lloret, M.A. Rivero-Crespo, A. Hirsch, A. Doménech-Carbó, G. Abellán, and A. Leyva-Pérez
JACS Au 2021, 1, 6, 786–794. DOI: 10.1021/jacsau.1c00107.
13. “Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions: from soluble to zeolite and MOF catalysts"
M.A. Rivero–Crespo,* J. Oliver-Meseguer, K. Kapłońska, P. Kuśtrowski, E. Pardo, J.P. Cerón-Carrasco and A. Leyva-Pérez
Chem. Sci. 2020, 11, 8113-8124. DOI: 10.1039/d0sc02391d.
12. “Intermolecular Carbonyl–Olefin Metathesis with Vinyl Ethers Catalyzed by Homogeneous and Solid Acids in Flow”
M.A. Rivero–Crespo,+ M. Tejeda-Serrano,+ H. Pérez-Sánchez, J.P. Cerón-Carrasco and A. Leyva-Pérez
Angew. Chem. Int. Ed. 2020, 59 (10), 3847-3849. DOI: 10.1002/anie.201909597.
11. “Nanoceria as a recyclable catalyst/support for the cyanosilylation of ketones and alcohol oxidation in cascade”
F Garnes-Portolés,+ M.A. Rivero-Crespo,+ A Leyva-Pérez
J. Catal. 2020, 392, 21-28. DOI: 10.1016/j.jcat.2020.09.032.
10. “Base–Controlled Heck, Suzuki and Sonogashira Reactions Catalyzed by Ligand–Free Sub–Nanometer Palladium or Platinum Clusters”
E. Fernández,+ M.A. Rivero–Crespo,+ I. Domínguez, P. Rubio–Marqués, J. Oliver–Meseguer, L. Liu, M. Cabrero–Antonino, R. Gavara, J.C. Hernández-Garrido, M. Boronat, A. Leyva–Pérez and A. Corma
J. Am. Chem. Soc. 2019, 141 (5), 1928-1940. DOI: 10.1021/jacs.8b07884.
9. “Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters”
V. Lloret,+ M.A. Rivero–Crespo,+ J.A. Vidal–Moya, S. Wild, F. Hauke, M. Varela, A. Hirsch, A. Leyva–Pérez and G. Abellán
Nat. Commun. 2019, 10, 509. DOI: 10.1038/s41467-018-08063-3.
8. “Lattice Opening Upon Bulk Reductive Covalent Functionalization of Black Phosphorus”
S. Wild, M. Fickert, A. Mitrovic, V. Lloret, C. Neiss, J.A. Vidal‐Moya, M.A. Rivero‐Crespo, A. Leyva‐Pérez, K. Werbach, H. Peterlik, M. Grabau, H. Wittkämper, C. Papp, H.P. Steinrück, T. Pichler, A. Görling, F. Hauke, G. Abellán, A. Hirsch.
Angew. Chem. Int. Ed. 2019, 58, 5763-5768. DOI: 10.1002/anie.201811181.

7. “Characterization of serpentines from different regions by transmission electron microscopy, X-ray diffraction, BET specific surface area and vibrational and electronic spectroscopy”
M.A. Rivero-Crespo, D.P. Gómez, M.V.V. García, J.M.G. Amores, V.S. Escribano
Fibers, 2019, 7 (5), 47. DOI: 10.3390/fib7050047.
6. “Confined Pt11+-water clusters in a Metal-Organic Framework Catalyze the Low-Temperature Water-Gas Shift Reaction with Waterborne CO2 Oxygen Atoms”
M.A. Rivero-Crespo,+ M. Mon,+ J. Ferrando–Soria, C. W. Lopes, M. Boronat, A. Leyva–Pérez, A. Corma, J.-C. Hernández-Garrido, M. López-Haro, J.-J. Calvino, E. V. Ramos-Fernandez, D. Armentano and E. Pardo.
Angew. Chem. Int. Ed. 2018, 57, 17094-17099. DOI: 10.1002/anie.201810251.
5. “Synthesis of Densely Packaged, Ultrasmall Pt02 Clusters within a Thioether‐Functionalized MOF: Catalytic Activity in Industrial Reactions at Low Temperature.”
M.A. Rivero-Crespo,+ M. Mon,+ J. Ferrando-Soria, A. Vidal-Moya, M. Boronat, A. Leyva-Pérez; A. Corma, J.-C. Hernández-Garrido, M. López-Haro, J.-J. Calvino, G. Ragazzon. A. Credi, D. Armentano and E. Pardo.
Angew. Chem. Int. Ed. 2018, 57 (21), 6186-6191. DOI: 10.1002/anie.201801957.
4. “Generation and Reactivity of Electron-Rich Carbenes on the Surface of Catalytic Gold Nanoparticles.”
J. Oliver-Meseguer, M. Boronat, A. Vidal-Moya, P. Concepción, M.A. Rivero-Crespo, A. Leyva-Pérez, A. Corma.
J. Am. Chem. Soc. 2018, 140 (9), 3215-3218. DOI: 10.1021/jacs.7b13696.
3. “A Ligand-Free Pt3 Cluster Catalyzes the Markovnikov Hydrosilylation of Alkynes with up to 106 Turnover Frequencies.”
M.A. Rivero-Crespo, A. Leyva-Pérez, A. Corma.
Chem. Eur. J. 2017, 23 (7), 1702-1708. DOI: 10.1002/chem.201605520.
2. “Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts.”
P. Rubio-Marqués, M.A. Rivero-Crespo, A. Leyva-Pérez, A. Corma.
J. Am. Chem. Soc. 2015, 137 (36), 11832-11837. DOI: 10.1021/jacs.5b07304.
1. “A study of commercial transition aluminas and of their catalytic activity in the dehydration of ethanol.”
T.K. Phung, A. Lagazzo, M.A. Rivero Crespo, V. Sánchez Escribano, G. Busca
J. Catal. 2014, 311, 102-113. DOI: 10.1016/j.jcat.2013.11.010.
Books and Book Chapters
1. “Ligand-free subnanometre gold metal clusters and their applications”
Corma, A.; Leyva-Perez, A.; Rivero-Crespo, M.A.
In Catalysis: Volume 30, The Royal Society of Chemistry: 2018; Vol. 30, pp 21-40. DOI: 10.1039/9781788013048
Patents
1. “Molecular sensors, method and kit for the detection and quantification of carbon dioxide”
International Patent Application PCT/EP2023/050923, European patent application EP22153468
Ori Green, Patrick Finkelstein, Miguel A. Rivero–Crespo, Marius D. R. Lutz, Michael K. Bogdos, Bill Morandi
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